The problem with increased greenhouse gases like

has nothing to do with breathability. But first, some corrections to your numbers. The Earth's atmosphere is nearly 80%

. Nearly 20% of the atmosphere is

. Even if you consumed all

by burning carbon, you would not raise the

level to 80%, not even close.
Look at the graph below.

is a tiny fraction of the atmosphere. That tiny fraction has oscillated up and down over the millennia. When it is down, we get ice ages. When it is up, we get periods of lush plant growth. Now look at the right hand side of the graph. Over the last 200 years, the concentration of

has skyrocketed.
Climate change deniers claim that our high

levels are part of natural variations and that there is no evidence of human intervention. Well, this graph clearly shows the natural variations in atmospheric

. We are now at twice maximum variation and increasing with no end in sight. I defy anyone to look at this graph and make a logical fact-based argument that the spike is due to natural variations.
This is one of many graphs of global

concentration that you can find
here.
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